A Metal-free Access to Hindered N-Alkyl Sulfoximines via In-Situ Generated Aza-Oxyallyl Cations from Functionalized Alkyl Bromide

被引：6
|
作者：
More, Satish G. [1 ,2 ]
Mane, Kishor D. [1 ,2 ]
Suryavanshi, Gurunath [1 ,2 ]
机构：
[1] CSIR, Natl Chem Lab, Chem Engn & Proc Dev Div, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, Uttar Pradesh, India
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 07期
关键词：
Aza-oxyallyl cations; alpha-Bromo hydroxamates; Di-alkyl sulfoximines; Metal-free; Sulfoximines; CYCLOADDITION REACTIONS; DISCOVERY; DERIVATIVES; INHIBITORS; AMINATION; ANALOGS;
D O I：
10.1002/ajoc.202200210
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Herein, we report a catalyst-free and mild synthetic method for the construction of hindered N-alkyl sulfoximines derivative. A wide range of hindered di-alkyl sulfoximines can be readily obtained from the reaction of alpha-bromo-hydroxamates with a variety of sulfoximines, including diaryl, aryl-alkyl, di-alkyl and heteroaryl sulfoximines.
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页数：5
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