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A Novel Method for the Synthesis Triarylphosphines under Transition-Metal-Free Conditions

被引：0
|
作者：
Yin, Qing [1 ]
Yu, Xiaoqiang [1 ]
Bao, Ming [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 39卷 / 10期
基金：
中国国家自然科学基金;
关键词：
transition metal-free; alkyldiphenylphosphines; aryl halides; triarylphosphines; C-P; PHOSPHINE OXIDES; COUPLING REACTIONS; SUBSTITUTED PHOSPHINES; SECONDARY PHOSPHINES; BOND FORMATION; REDUCTION; ARYL; TERTIARY; HALIDES;
D O I：
10.6023/cjoc201904006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Triarylphosphines play an important role in pharmaceutical synthesis and transition-meal-catalyzed reactions. In this paper, a novel method for the synthesis of triatylphosphines via base-promoted C(sp(2))-P cross-coupling reactions of alkyldiphenylphosphines with aryl halides is described. The transition-metal-free reaction condition, readily available starting materials and experimental simplicity are the features of the novel method.
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收藏
页码：2930 / 2935
页数：6
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