An expeditious synthesis of tailed tren-capped porphyrins

被引:9
|
作者
Even, P [1 ]
Ruzié, C [1 ]
Ricard, D [1 ]
Boitrel, B [1 ]
机构
[1] Univ Rennes 1, Inst Chim, UMR CNRS 6509, F-35042 Rennes, France
关键词
D O I
10.1021/ol0513802
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
graph A one-pot two-step versatile synthesis of tailed tren-capped porphyrins has been achieved. The two resulting ligands demonstrate that this expeditious method can be applied to various axial bases to obtain highly functionalized macromolecules attractive for heme modeling purposes. Dioxygen binding of the pyridine-tailed iron complex is reported as a direct application.
引用
收藏
页码:4325 / 4328
页数:4
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