Water-based synthesis and characterisation of a new Zr-MOF with a unique inorganic building unit

被引：52
|
作者：
Waitschat, S. [1 ]
Reinsch, H. [1 ]
Stock, N. [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 86期
关键词：
METAL-ORGANIC FRAMEWORKS; ADSORPTION; STABILITY; TOPOLOGY; CLUSTERS; FEATURES; ACID; CO2;
D O I：
10.1039/c6cc06287c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new, microporous Zr-MOF was obtained using 2,5-pyrazinedicarboxylic acid (H(2)PzDC). The linker leads to the formation of a new 1D inorganic building unit composed of l-OH bridged {Zr6O4(OH4)} clusters which are arranged in a hexagonal array and connected by the PzDC(2-) ions. The structure was determined from powder X-ray diffraction data.
引用
收藏
页码：12698 / 12701
页数：4
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