Synthesis and Structural Characterization of Two New Layered Inorganic-Organic Hybrid Zinc Phosphites Templated by Cyclam: Zn(HPO3)2•0.5(C10H28N4) and Zn2(HPO3)3•0.5(C10H28N4)

被引：6
|
作者：
Halime, Ilham [2 ]
Bezgour, Abdoulillah [2 ]
Fahim, Mohammed [3 ]
Dusek, Michal [4 ]
Fejfarova, Karla [4 ]
Lachkar, Mohammed [2 ]
El Bali, Brahim [1 ]
机构：
[1] Univ Mohamed I, LMSAC, Dept Chem, Fac Sci, Oujda 60000, Morocco
[2] Univ Sidi Mohamed Ben Abdellah, Lab Ingn Mat Organometall & Mol, Unite Associee CNRST URAC 19, Fac Sci Dhar El Mahraz, Fes 30000, Morocco
[3] Univ Moulay Ismail, Fac Sci, Meknes, Morocco
[4] Inst Phys, Prague 18221 8, Czech Republic
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 02期
关键词：
Hybrid phosphates; Cyclam; Wet chemistry; Single crystal structure; IR spectroscopy; HPO3 PSEUDO PYRAMIDS; HYDROTHERMAL SYNTHESIS; MESOPOROUS MATERIALS; CRYSTAL-STRUCTURE; ZNO4; TETRAHEDRA; ZINCOPHOSPHITE; CATALYSIS; NETWORKS; HYDROGEN;
D O I：
10.1007/s10870-010-9868-6
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Using 1,4,8,11-tetraazacyclotetradecane (cyclam) as a template, two new layered zincophosphites, Zn(HPO3)(2)center dot 0.5(C10H28N4) (1) and Zn-2(HPO3)(3)center dot 0.5(C10H28N4) (2), were synthesized and characterized by single crystal X-ray diffraction. The two new compounds crystallize in the triclinic system with the space group P - 1 and the cell parameters: a = 8.3130 angstrom, b = 8.7289 angstrom, c = 9.0055 angstrom, alpha = 106.90(1), beta = 95.56(1), gamma = 105.30(1), V = 592.31 angstrom(3), Z = 2 for 1 and a = 9.0406 angstrom, b = 9.4234 angstrom, c = 9.4519 angstrom, alpha = 91.19(1), beta = 100.73(1), gamma = 106.85(1), V = 754.82 angstrom(3), Z = 2 for 2. Both structures are described in terms of phosphometallic slabs hosting the cyclam cation.
引用
收藏
页码：223 / 229
页数：7
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