Catalytic σ-Bond Metathesis

被引：35
|
作者：
Reznichenko, Alexander L. [1 ]
Hultzsch, Kai C. [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
来源：
MOLECULAR CATALYSIS OF RARE-EARTH ELEMENTS | 2010年 / 137卷
关键词：
C-H activation; Catalysis; Cyclization; Hydroalkoxylation; Hydroamination; Hydroboration; Hydrogenation; Hydrophosphination; Hydrosilylation; Hydrostannation; C-H BOND; DIVERSE MECHANISTIC PATHWAYS; MEDIATED INTRAMOLECULAR HYDROAMINATION/CYCLIZATION; DENSITY-FUNCTIONAL CHARACTERIZATION; YTTRIUM HYDRIDO COMPLEXES; EARTH-METAL ALKYL; RARE-EARTH; CARBON-CARBON; ASYMMETRIC HYDROAMINATION; INTERMOLECULAR HYDROPHOSPHINATION;
D O I：
10.1007/430_2010_17
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This account summarizes information on recently reported applications of organo-rare-earth metal complexes in various catalytic transformations of small molecules. The sigma-bond metathesis at d(0) rare-earth metal centers plays a pivotal role in carbon-carbon and carbon-heteroatom bond forming processes. Relevant mechanistic details are discussed and the focus of the review lies in practical applications of organo-rare-earth metal complexes.
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页码：1 / 48
页数：48
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