The heat capacity and thermodynamic functions of cerussite

被引：11
|
作者：
Bissengaliyeva, Mira R. [1 ]
Gogol, Daniil B. [1 ]
Taimassova, Shynar T. [1 ]
Bekturganov, Nuraly S. [2 ]
机构：
[1] Inst Problems Complex Dev Mineral Resources, Karaganda 100019, Kazakhstan
[2] SC Natl Sci Technol Holding Parasat, Astana 010000, Kazakhstan
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2012年 / 47卷
关键词：
Adiabatic calorimetry; Thermodynamic functions; Lead carbonate; TEMPERATURE-RANGE; CALORIMETRY; MINERALS; RAMAN; LEAD;
D O I：
10.1016/j.jct.2011.10.014
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The heat capacity of natural lead carbonate (cerussite, PbCO3) has been measured by means of the low-temperature adiabatic calorimetry over the temperature range of (4 to 320) K. Its thermodynamic functions Cp(T), S(T) and H(T)-H(0) have been calculated over the whole temperature range from the experimental data on the heat capacity. The standard values of the heat capacity and entropy are equal to C-p,C-m degrees = 87.07 +/- 0.09 J.mol(-1).K-1, S-m degrees = 125.45 +/- 0.20 J.mol(-1)K(-1), respectively. An anomalous deviation of the heat capacity has been registered in the range of (269 to 278) K. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：197 / 202
页数：6
相关论文
共 50 条
  • [1] Heat Capacity and Thermodynamic Functions of Diphenylacetylene
    Tkachenko, Ekaterina S.
    Varushchenko, Raisa M.
    Druzhinina, Anna I.
    Reshetova, Marina D.
    Borisova, Nataliya E.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (12): : 4700 - 4709
  • [2] Heat Capacity and Thermodynamic Functions of PdS
    Polotnyanko, N. A.
    Tyurin, A., V
    Chareev, D. A.
    Khoroshilov, A., V
    INORGANIC MATERIALS, 2020, 56 (07) : 683 - 689
  • [3] Heat capacity and thermodynamic functions of ferrocenemethanol
    Krol O.V.
    Druzhinina A.I.
    Varushchenko R.M.
    Dorofeeva O.V.
    Reshetova M.D.
    Borisova N.E.
    Moscow University Chemistry Bulletin, 2007, 62 (6) : 306 - 312
  • [4] Heat Capacity and Thermodynamic Functions of PdS
    N. A. Polotnyanko
    A. V. Tyurin
    D. A. Chareev
    A. V. Khoroshilov
    Inorganic Materials, 2020, 56 : 683 - 689
  • [5] The heat capacity and thermodynamic functions of tripropylarsine
    Sheiman, V.M.
    Karyakin, N.V.
    Sheiman, M.S.
    Zelyaev, I.A.
    Zhurnal Fizicheskoj Khimii, 2002, 76 (06): : 992 - 996
  • [6] Heat Capacity and Thermodynamic Functions of Diethyl Telluride
    Sheiman, M. S.
    Kamelova, G. P.
    Shvetsova, K. G.
    Nistratov, V. P.
    Russian Journal of Physical Chemistry, 70 (07):
  • [7] Heat capacity and thermodynamic functions of triethyl phosphine
    Sheiman, MS
    Kamelova, GP
    Zelyaev, IA
    Sheiman, VM
    ZHURNAL FIZICHESKOI KHIMII, 1999, 73 (04): : 598 - 601
  • [8] Heat Capacity and Thermodynamic Functions of Neodymium Orthoniobate
    Nikiforova, G. E.
    Kondrat'eva, O. N.
    Tyurin, A. V.
    Ryumin, M. A.
    Khoroshilov, A. V.
    Gavrichev, K. S.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 66 (02) : 237 - 244
  • [9] HEAT CAPACITY AND THERMODYNAMIC FUNCTIONS OF POLYVINYL ALCOHOL
    WARFIELD, RW
    BROWN, R
    KOLLOID-ZEITSCHRIFT AND ZEITSCHRIFT FUR POLYMERE, 1962, 185 (01): : 63 - &
  • [10] Heat capacity and thermodynamic functions of diethyl telluride
    Sheiman, MS
    Kamelova, GP
    Shvetsova, KG
    Nistratov, VP
    ZHURNAL FIZICHESKOI KHIMII, 1996, 70 (07): : 1190 - 1193
12345