Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate))

被引：34

作者：

Shekurov, Ruslan ^{[1
]}

Miluykov, Vasily ^{[1
]}

Kataeva, Olga ^{[1
,2
]}

Krivolapov, Dmitry ^{[1
]}

Sinyashin, Oleg ^{[1
]}

Gerasimova, Tatiana ^{[1
]}

Katsyuba, Sergey ^{[1
]}

Kovalenko, Valeri ^{[1
]}

Krupskaya, Yulia ^{[3
]}

Kataev, Vladislav ^{[3
]}

Buechner, Bernd ^{[3
,4
]}

Senkovska, Irena ^{[5
]}

Kaskel, Stefan ^{[5
]}

机构：

[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Arbuzov Str 8, Kazan 420088, Russia

[2] Kazan Fed Univ, AM Butlerov Chem Inst, Kremlevskaya Str 18, Kazan 420000, Russia

[3] IFW Dresden, Helmholtzstr 20, D-01087 Dresden, Germany

[4] Tech Univ Dresden, Inst Solid State Phys, D-01069 Dresden, Germany

[5] Tech Univ Dresden, Dept Inorgan Chem, Bergstr 66, D-01062 Dresden, Germany

来源：

CRYSTAL GROWTH & DESIGN | 2016年 / 16卷 / 09期

基金：

俄罗斯科学基金会; 俄罗斯基础研究基金会;

关键词：

METAL-ORGANIC FRAMEWORK; HIGH-CAPACITY; CRYSTAL; NETWORKS; CU(II); CHAINS; ACID; SIZE;

D O I：

10.1021/acs.cgd.6b00681

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A flexible and hydrolytically stable metal organic framework [Mn(H2O)(2)(FC(PHOO)(2))center dot 2H(2)O](n) has been synthesized using ferrocene-based ligand bearing phosphinic groups (Fc(PHOOH)(2) = 1,1'-ferrocenediyl-bis(H-phosphinic acid)). In this compound manganese atoms are bound by phosphinate fragments to give infinite chains, and the latter are interconnected by ferrocene groups to form two-dimensional coordination polymer. The elimination of both coordinated and lattice water molecules during heating up to 150 degrees C produced the compound, which is nonporous for nitrogen, but can selectively adsorb water over methanol and other solvents at 298 K. The reversible structural transformation during adsorption/desorption of water is also reflected in a change of magnetic properties of the metal-organic framework.

引用

页码：5084 / 5090

页数：7

共 16 条

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