Distribution of cyclic volatile methylsiloxanes in drinking water, tap water, surface water, and wastewater in Hanoi, Vietnam

In this study, four cyclic volatile methylsiloxanes (cVMSs) were determined in drinking water, tap water, surface water, and wastewater samples collected from Hanoi metropolitan area, Vietnam, during August to December 2020 (dry season) by using solid phase extraction combined with gas chromatography tandem mass spectrometry. Highest concentrations of cVMSs in the range of 63-7400 ng/L (mean/median: 1840/1310 ng/L) were found in wastewater samples. A significant difference existed in the concentrations of cVMSs between influent and effluent of a wastewater treatment plant. The sum concentrations of four cVMSs in lake water, tap water, and bottled water samples were in the ranges of 67.0-1100 ng/L (mean/median: 350/282 ng/L), 19.8-350 ng/L (12.6/12.3 ng/L), and 2.31-28.1 ng/L (10.3/8.23 ng/L), respectively. Among the four cVMSs, decamethylcyclopentasiloxane (D5) was found at the highest concentrations in all water samples analyzed. The mean exposure doses of cVMSs calculated for adults and children through the consumption of drinking were 0.409 and 0.412 ng/kg-bw/day, respectively. Human exposure to cVMSs calculated through drinking water consumption was significantly lower than that reported for inhalation.