A Bimetallic Chain Based on [Mo(CN)8]3- and Ho3+ Ions as Building Blocks

被引：0
|
作者：
Ren, Shi [1 ]
Ma, Yin [1 ]
Ma, Shu-Lin [1 ]
机构：
[1] Tianjin Univ Commerce, Coll Sci, Dept Applicat Chem, Tianjin 300134, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 09期
关键词：
cyano bridge; H-bonding; octacyanomolybdate(V)-based; rare earth ion; 1D zigzag-like chain; COORDINATION POLYMERS; LUMINESCENT; MAGNETISM; CO; SM;
D O I：
10.1080/15533174.2011.591644
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel bimetallic 4d-4f complex, {[Ho-III(DMF)(6)] [Mo-V(CN)(8)]center dot 3H(2)O}(n) (1) (DMF = N,N'-dimethylformamide), has been synthesized and structurally characterized. The crystalline analyses shown that the complex 1 consists of a one-dimensional (1D) infinite chain, which adopts a 1D zigzag motif, and this is the first structurally characterized example of a 1D structure based on the [Mo(CN)(8)](3-) and Ho3+ building blocks. The complex 1 crystallizes in a monoclinic system of space group P2(1)/c, with a = 10.8672(7), b = 20.920(2), c = 17.9097(7) angstrom, beta = 92.646(4)degrees, and Z = 4.
引用
收藏
页码：1167 / 1171
页数：5
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