IR Microscopy as a Method for Studying the Influence of An External Electric Field on the Spin Crossover Exemplified by the Fe(II) Complex with 2,6-Bis(pyrazol-1-yl)pyridine

被引：3
|
作者：
Minakova, O. V. [1 ,2 ]
Tumanov, S. V. [1 ,2 ]
Fedin, M. V. [1 ,2 ]
Veber, S. L. [1 ,2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Int Tomog Ctr, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2020年 / 46卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
coordination compounds; spin crossover; iron(II); FT-IR microscopy;
D O I：
10.1134/S1070328420040041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The influence of the electric field on the spin state of the single crystal of [Fe(1-Bpp)(2)][BF4](2) demonstrating the spin crossover phenomenon is studied. The spin state of the complex is determined by the indirect method: FT-IR microscopy. The experimental results show that the application of the external electrostatic field with an intensity of 13 kV/cm exerts no effect on the temperature of the magnetostructural transition of the compound within 0.2 K.
引用
收藏
页码：326 / 329
页数：4
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