The formation and stability of molybdenum-antimony and tungsten-antimony ternary oxides Sb2MO6, Sb2M2O9, Sb2Mo3O12 and Sb4MO9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

被引：4
|
作者：
Berezovskaya, E. [1 ]
Milke, E. [1 ]
Binnewies, M. [1 ]
机构：
[1] Leibniz Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 35期
关键词：
SUBLIMATION; TRIOXIDE; THERMODYNAMICS; APPROXIMATION; VAPORIZATION; EQUILIBRIUM; CHLORIDE; SPECTRA; SYSTEMS; ENERGY;
D O I：
10.1039/c2dt31058a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The ternary oxides Sb2MO6, Sb2M2O9, Sb4MO9 (M = Mo, W) and Sb2Mo3O12 were detected in the gas phase by means of mass spectrometry (MS). These gaseous oxides are reported for the first time. Thermodynamic data was obtained experimentally and confirmed by quantum chemical (QC) calculations. In addition, structural data on these molecules was obtained. The ionisation potentials (IP) were also determined both experimentally and theoretically.
引用
收藏
页码：10769 / 10776
页数：8
相关论文
共 50 条
  • [1] STUDY OF SB-MO-O SYSTEM AT 500-DEGREES-C - DETECTION OF 2 NEW MOLYBDENUM ANTIMONY OXIDES
    PARMENTIER, M
    GLEITZER, C
    TILLEY, RJD
    JOURNAL OF SOLID STATE CHEMISTRY, 1980, 31 (03) : 305 - 311
  • [2] SYNTHESIS OF THE NOVEL ORGANOMETALLIC MOLYBDENUM-ANTIMONY CLUSTER, (MU-4-SB)2CP4MO5(CO)14
    GORZELLIK, M
    NUBER, B
    ZIEGLER, ML
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 431 (02) : 171 - 176
  • [3] Raman studies of supported V, Cr and Sb oxides and their mechanical mixture with α-Bi2Mo3O12
    Corberán, VC
    Savkin, VV
    Ruiz, P
    Vislovskii, VP
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 158 (01) : 271 - 274
  • [4] ON SOME NEW TERNARY OXYGENATED PHASES OF SYSTEMS A2O-MO3 WITH FORMULAE A4MO5 AND A6MO6 (A=LI,NA - M=MO,W)
    REAU, JM
    FOUASSIE.C
    HAGENMUL.P
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1967, (10): : 3873 - &
  • [5] Sulfur-bridged sandwich cubane-type molybdenum-antimony cluster.: Synthesis, X-ray structure, and 121Sb Mossbauer spectra of [H2O)9Mo3S4SbS4Mo3(H2O)9](CH3C6H4SO3)8•24H2O
    Sakane, G
    Hashimoto, K
    Takahashi, M
    Takeda, M
    Shibahara, T
    INORGANIC CHEMISTRY, 1998, 37 (17) : 4231 - 4234
  • [6] Spectroscopic properties of Nd3+ ions in Li2O-MO (M=Mg, Ca and Sr)-Sb2O3 glasses
    Asirvadam, A.
    Kumar, Valluri Ravi
    Reddy, B. Naveen Kumar
    Raju, G. Naga
    Prasad, P. Syam
    Rao, P. Venkateswara
    OPTIK, 2022, 264
  • [7] Optical and luminescence properties of Er3+ doped Sb2O3-Li2O-MO (M=Mg, Ca and Sr) glasses
    Asirvadam, A.
    Kumar, Valluri Ravi
    Nagarjuna, M.
    Raju, G. Naga
    Prasad, P. Syam
    Baskaran, G. Sahaya
    Kumar, V. Ravi
    Rao, P. Venkateswara
    OPTICAL MATERIALS, 2022, 128
  • [8] CATALYTIC PROPERTIES OF ORTHORHOMBIC TUNGSTEN OR MOLYBDENUM BRONZES (SB(III)2O)MO10O30, (BI(III)2O)W10O30
    FORISSIER, M
    FAI, NC
    GANNE, M
    TOURNOUX, M
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1989, (06): : 745 - 752
  • [9] Reactions of an antimony containing cage compound with metal carbonyls:: synthesis and structural characterization of [{M(CO)5}2(η1:η1-P4Sb2C4But4)], M = Cr, Mo or W, and [{Fe(CO)4}2{Fe(CO)3(η3:η1-P4Sb2C4But4)}]
    Hibbs, DE
    Hursthouse, MB
    Jones, C
    Thomas, RC
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (15): : 2627 - 2631
  • [10] Influence of WO3 on some physical properties of MO-Sb2O3-B2O3 (M = Ca, Pb and Zn) glass system
    Gandhi, Y.
    Sudhakar, K. S. V.
    Nagarjuna, M.
    Veeraiah, N.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 485 (1-2) : 876 - 886
12345