Unusual Ion UO4- Formed Upon Collision Induced Dissociation of [UO2(NO3)3]-, [UO2(ClO4)3]-, [UO2(CH3COO)3]- Ions

被引：17

作者：

Sokalska, Marzena ^{[1
]}

Prussakowska, Malgorzata ^{[1
]}

Hoffmann, Marcin ^{[1
]}

Gierczyk, Blazej ^{[1
]}

Franski, Rafal ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

来源：

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY | 2010年 / 21卷 / 10期

关键词：

GAS-PHASE; MASS-SPECTROMETRY; CRYSTAL-CHEMISTRY; URANYL COMPLEXES; AB-INITIO; URANIUM; NITRATE; SPECIATION; PEROXIDES; MOLECULES;

D O I：

10.1016/j.jasms.2010.06.018

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The following ions [UO2(NO3)(3)](-), [UO2(ClO4)(3)](-), [UO2(CH3COO)(3)](-) were generated from respective salts (UO2(NO3)(2), UO2(ClO4)(3), UO2(CH3COO)(2)) by laser desorption/ionization (LDI). Collision induced dissociation of the ions has led, among others, to the formation of UO4- ion (m/z 302). The undertaken quantum mechanical calculations showed this ion is most likely to possess square planar geometry as suggested by MP2 results or strongly deformed geometry in between tetrahedral and square planar as indicated by DFT results. Interestingly, geometrical parameters and analysis of electron density suggest it is an U-VI compound, in which oxygen atoms bear unpaired electron and negative charge. (J Am Soc Mass Spectrom 2010, 21, 1789-1794) (C) 2010 American Society for Mass Spectrometry

引用

页码：1789 / 1794

页数：6

共 50 条

[1] Synthesis and crystal structure of (NH4)3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)]
L. B. Serezhkina
E. V. Peresypkina
A. V. Virovets
M. O. Karasev
Crystallography Reports, 2010, 55 : 19 - 23
[2] Crystal Structure of Rb-3[UO2(CH3COO)(3)](2)[UO2(CH3COO)(NCS)(2)(H2O)]
Serezhkina, L. B.
Vologzhanina, A. V.
Karasev, M. O.
Serezhkin, V. N.
RADIOCHEMISTRY, 2012, 54 (06) : 521 - 524
[3] Crystal structure of Rb3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)]
L. B. Serezhkina
A. V. Vologzhanina
M. O. Karasev
V. N. Serezhkin
Radiochemistry, 2012, 54 (6) : 521 - 524
[4] Synthesis and X-ray diffraction study of cs3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)] and Cs5[UO2(CH3COO)3]3[UO2(NCS)4(H2O)] · 2H2O
L. B. Serezhkina
E. V. Peresypkina
M. O. Karasev
A. V. Virovets
V. N. Serezhkin
Russian Journal of Inorganic Chemistry, 2013, 58 : 160 - 165
[5] Synthesis and X-ray diffraction study of cs3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)] and Cs5[UO2(CH3COO)3]3[UO2(NCS)4(H2O)] • 2H2O
Serezhkina, L. B.
Peresypkina, E. V.
Karasev, M. O.
Virovets, A. V.
Serezhkin, V. N.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (02) : 160 - 165
[6] SYNTHESIS AND STUDY OF NH4[UO2(CH3COO)3]
DUBROVIN, AV
ZHIROV, AI
MAZO, GN
SANTALOVA, NA
DUNAEVA, KM
SOVIET RADIOCHEMISTRY, 1986, 28 (02): : 135 - 139
[7] Synthesis and Crystal Structure of (NH4)3 [UO2(CH3COO)3]2[UO2(CH3 COO)(NCS)2(H2O)]
Serezhkina, L. B.
Peresypkina, E. V.
Virovets, A. V.
Karasev, M. O.
CRYSTALLOGRAPHY REPORTS, 2010, 55 (01) : 19 - 23
[8] The Uranium(VI) Oxoazides [UO2(N3)2•CH3CN], [(bipy)2(UO2)2(N3)4], [(bipy)UO2(N3)3]-, [UO2(N3)4]2-, and [(UO2)2(N3)8]4-
Haiges, Ralf
Vasiliu, Monica
Dixon, David A.
Christe, Karl O.
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (03) : 652 - 664
[9] ELECTRON-PARAMAGNETIC-RES STUDY OF THE NO3 RADICAL IN IRRADIATED K(UO2)(NO3)3, K2(UO2)(NO3)4, AND (NH4)2(UO2)(NO3)4 SINGLE-CRYSTALS
RAO, TKG
LINGAM, KV
BHATTACHARYA, BN
JOURNAL OF MAGNETIC RESONANCE, 1981, 45 (03) : 422 - 431
[10] Collision-induced dissociation of [UO2(NO3)3]- and [UO2(NO3)2(O2)]- and reactions of product ions with H2O and O2
Bubas, Amanda R.
Perez, Evan
Metzler, Luke J.
Rissler, Scott D.
Van Stipdonk, Michael J.
JOURNAL OF MASS SPECTROMETRY, 2021, 56 (03):

← 1 2 3 4 5 →