Decomposition products of KF • H2O2 studied by X-ray powder diffraction

被引：0
|
作者：
Titova, KV [1 ]
Nikol'skaya, VP
Buyanov, VV
Pudova, OV
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
[2] FGUP State Inst Biol Instrument Design, Moscow, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 50卷 / 04期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The composition of decomposition products of KF center dot H2O2 is studied by X-ray diffraction analysis. It is shown that, on heating to 140 degrees C under polythermal conditions, the peroxo solvate decomposes to form anhydrous potassium fluoride. The decomposition is accompanied by the appearance of extra reflections, which are presumably due to products of partial KF hydrolysis. Upon prolonged storage (for 3 or 4 years) of the peroxo solvate at 20 degrees C or upon its decomposition at 80 degrees C under isothermal conditions, potassium fluoride is isolated as a new previously unknown crystalline phase.
引用
收藏
页码：639 / 641
页数：3
相关论文
共 50 条
  • [1] X-RAY AND NEUTRON-DIFFRACTION STUDY OF KF.2H2O2
    SARIN, VA
    DUDAREV, VY
    DOBRYNINA, TA
    FYKIN, LE
    ZAVODNIK, VE
    KRISTALLOGRAFIYA, 1976, 21 (05): : 929 - 936
  • [2] Powder X-ray diffraction of Metastudtite, (UO2)O2(H2O)2
    Rodriguez, Mark A.
    Weck, Philippe E.
    Sugar, Joshua D.
    Kulp, Thomas J.
    POWDER DIFFRACTION, 2016, 31 (01) : 71 - 72
  • [3] Powder X-ray diffraction of altrenogest, C21H26O2
    Kaduk, James A.
    Gindhart, Amy M.
    Gates-Rector, Stacy
    Blanton, Thomas N.
    POWDER DIFFRACTION, 2022, 37 (04) : 240 - 241
  • [4] Structure of Ag2Ce(H2O)(NO3)(5) and its thermal decomposition studied by temperature-dependent X-ray powder diffraction
    Audebrand, N
    Auffredic, JP
    Louer, D
    JOURNAL OF SOLID STATE CHEMISTRY, 1997, 132 (02) : 361 - 371
  • [5] Decomposition of TiH2 studied in situ by synchrotron X-ray and neutron diffraction
    Jimenez, C.
    Garcia-Moreno, F.
    Pfretzschner, B.
    Klaus, M.
    Wollgarten, M.
    Zizak, I.
    Schumacher, G.
    Tovar, M.
    Banhart, J.
    ACTA MATERIALIA, 2011, 59 (16) : 6318 - 6330
  • [6] Multilayer relaxation of Ru(0001)-(2 x 2)-O studied by surface X-ray diffraction
    Nakamura, Masashi
    Kato, Hayato
    Hoshi, Nagahiro
    Sumitani, Kazushi
    Sakata, Osami
    JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (02): : 977 - 980
  • [7] X-ray powder diffraction data for κ-Al2O3
    Halvarsson, M
    Langer, V
    Vuorinen, S
    POWDER DIFFRACTION, 1999, 14 (01) : 61 - 63
  • [8] X-ray powder diffraction study of LiCrP2O7
    Ivashkevich, Ludmila S.
    Selevich, Kirill A.
    Lesnikovich, Anatoly I.
    Selevich, Anatoly F.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : i70 - i72
  • [9] Decomposition in Prolonged Storage of KF · H2O2 Stabilized with Carboxylic Acids
    K. V. Titova
    V. P. Nikol’skaya
    V. V. Buyanov
    O. B. Pudova
    G. P. Karzhavina
    Russian Journal of Applied Chemistry, 2005, 78 : 281 - 285
  • [10] Decomposition in prolonged storage of KF • H2O2 stabilized with carboxylic acids
    1600, Maik Nauka-Interperiodica Publishing (78):
12345