A potentiometric and spectroscopic study of copper(II) diaminodioxime complexes

被引：27
|
作者：
Jackson, GE [1 ]
Nakani, BS [1 ]
机构：
[1] UNIV TRANSKEI, DEPT CHEM, ZA-5100 Umtata, SOUTH AFRICA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 07期
关键词：
D O I：
10.1039/dt9960001373
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Copper(II) and H+ complexes of 3,3,8,8-tetramethyl-4,7-diazadecane-2,9-dione dioxime, 3,3,9,9-tetramethyl-4,8-diazaundecane-2, 10-dione dioxime and 3,3,10,10-tetramethyl-4,9-diazadodecane-2, 11-dione dioxime have been studied at 25 degrees C and ionic strength 0.15 mol dm(-3) NaCl, using glass-electrode potentiometry. Electronic spectra have been used to postulate structures for the different species in solution. In each case the metal binds to the four nitrogen atoms of the oxime. In the MLH(-1) species hydrogen bonding between the terminal oxime groups produces a pseudo-macrocycle. Computer simulation has been used to predict the effect of the ligands on the blood-plasma metal-ion distribution in vivo.
引用
收藏
页码：1373 / 1377
页数：5
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