Rhodium(III) complexes containing acetylacetonate and mono- or bidentate ligands

被引：0
|
作者：
Sarkhel, P [1 ]
Paul, BC [1 ]
Poddar, RK [1 ]
机构：
[1] NE Hill Univ, Dept Chem, Shillong 793003, Meghalaya, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1999年 / 38卷 / 02期
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Rh(III) complex, viz., [RhCl2(acac)(acacH)] (acacH = acetylacetone) has been isolated in high yield by the reaction of RhCl3 with acacH. The compound is a convenient starting material for the synthesis of a variety of Rh(III) complexes, vit., [RhX2(acac)L-2] (X = Cl or Br; L = PPh3, AsPh3 or py), [RhX2(acac)(L-L)] (X = Cl or Br; L-L = bipy or phen) and M-2[RhCl4(acac)] (M = NMe4 or Cs). These compounds have been characterised using analytical data, physico-chemical, spectroscopic and electrochemical techniques.
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页码：150 / 155
页数：6
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