Understanding Oxotransferase Reactivity in a Model System Using Singular Value Decomposition Analysis

被引：0
|
作者：
Kail, Brian W. [1 ]
Young, Charles G.
Johnson, Mitchell E. [1 ]
Basu, Partha [1 ]
机构：
[1] Duquesne Univ, Dept Chem & Biochem, Pittsburgh, PA 15282 USA
来源：
BIOINORGANIC CHEMISTRY: CELLULAR SYSTEMS AND SYNTHETIC MODELS | 2009年 / 1012卷
关键词：
OXYGEN-ATOM-TRANSFER; CYTOCHROME-C-OXIDASE; DIFFERENCE SPECTRA; COMPLEX; KINETICS; MOLYBDENUM(VI); INTERMEDIATE; COMPONENTS;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Singular value decomposition (SVD) analysis on spectrophotometric data obtained from an oxygen atom transfer (OAT) reaction involving a molybdoenzyme model system is reported. Specifically, the rate of solvolysis reaction of a phosphoryl intermediate complex has been compared with independent measurements. The SVD derived reaction rates are consistent with other measurements. This generalized approach is applicable in examining other bioinorganic reactions, and data processing.
引用
收藏
页码：199 / 217
页数：19
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