Simple and improved regioselective brominations of aromatic compounds using N-benzyl-N,N-dimethylanilinium peroxodisulfate in the presence of potassium bromide under mild reactions conditions

被引：2

作者：

Ghasemnejad-Bosra, Hassan ^{[1
]}

Ramzanian-Lehmali, Farhad ^{[2
]}

Jafari, Somaye ^{[1
]}

机构：

[1] Islamic Azad Univ, Babol Branch, Sch Sci, Babol Sar, Iran

[2] Univ Payamenoor, Babol Sar, Iran

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2011年 / 76卷 / 05期

关键词：

bromination; N-benzyl-N; N-dimethylanilinium peroxodisulfate; potassium bromide; phenols; methoxyarenes; OXIDATIVE DEPROTECTION; BENZYLTRIPHENYLPHOSPHONIUM PEROXODISULFATE; NUCLEAR BROMINATION; N-BROMOSUCCINIMIDE; CARBONYL-COMPOUNDS; REAGENT; EFFICIENT; IODINATION; ETHERS; TRIMETHYLSILYL;

D O I：

10.2298/JSC100212058G

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple, efficient, and mild method for the selective bromination of some activated aromatic compounds using N-benzyl-N,N-dimethylanilinium peroxodisulfate in the presence of potassium bromide in non-aqueous solution is reported. The results obtained revealed good to excellent seleetivity between the ortho and para positions of phenols and methoxyarenes.

引用

页码：685 / 692

页数：8

共 18 条

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