Interfacially Interactive Ternary Silver-Supported Polyaniline/Multiwalled Carbon Nanotube Nanocomposites for Catalytic and Antibacterial Activity

被引:67
|
作者
Deshmukh, Shamkumar P. [1 ,2 ]
Dhodamani, Ananta G. [1 ]
Patil, Satish M. [1 ,3 ]
Mullani, Sajid B. [1 ]
More, Krantiveer, V [1 ]
Delekar, Sagar D. [1 ]
机构
[1] Shivaji Univ, Dept Chem, Kolhapur 416001, Maharashtra, India
[2] DBF Dayanand Coll Arts & Sci, Dept Chem, Solapur 413001, Maharashtra, India
[3] Karmaveer Hire Arts Sci Commerce & Educ Coll, Dept Chem, Kolhapur 416209, Maharashtra, India
来源
ACS OMEGA | 2020年 / 5卷 / 01期
关键词
AG NANOPARTICLES; GOLD NANOPARTICLES; AU NANOPARTICLES; GRAPHENE OXIDE; POLYANILINE; REDUCTION; EFFICIENT; POLYMERIZATION; 4-NITROPHENOL; PERFORMANCE;
D O I
10.1021/acsomega.9b02526
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, a protocol strategy has been designed for the preparation of ternary silver nanoparticles-supported polyaniline multiwalled carbon nanotube (Ag NPs-PANI/MWCNT) nanocomposites with a chemical interaction for catalytic and antibacterial activity. The morphological study confirmed that Ag NPs were immobilized on the surface of PANI, and afterward, Ag NPs-PANI were mixed with the MWCNTs. The X-ray diffraction technique revealed the face-centered cubic structure of Ag NPs, and the X-ray photoelectron spectroscopy study revealed the chemical constituent and signature of pi-pi* and C-N interactions in the nanocomposites. The ternary Ag NPs-PANI/MWCNTs nanocomposites have the apparent rate of reaction (K-app) as 5.4 x 10(-3) s(-1), higher than binary nanocomposites for catalytic reduction of 4-nitrophenol to 4-aminophenol at room temperature. Antibacterial activity of Ag NPs-PANI/MWCNT nanocomposites is higher against pathogenic bacteria. Thereafter, because of multifold applications of ternary nanocomposites, they have a broad scope in the field of environmental and healthcare sectors.
引用
收藏
页码:219 / 227
页数:9
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