Microwave-assisted green synthesis of uniform Ru nanoparticles supported on non-functional carbon nanotubes for cinnamaldehyde hydrogenation

被引：50

作者：

Ni, Xiaojuan

Zhang, Bingsen ^{[2
]}

Li, Chuang

Pang, Min

Su, Dangsheng ^{[2
]}

Williams, Christopher T. ^{[3
]}

Liang, Changhai ^{[1
]}

机构：

[1] Dalian Univ Technol, Lab Adv Mat & Catalyt Engn, Sch Chem Engn, Dalian 116024, Peoples R China

[2] Max Planck Gesell, Dept Inorgan Chem, Fritz Haber Inst, D-14195 Berlin, Germany

[3] Univ S Carolina, Dept Chem Engn, Columbia, SC 29208 USA

来源：

CATALYSIS COMMUNICATIONS | 2012年 / 24卷

基金：

中国国家自然科学基金;

关键词：

Microwave-assisted thermolysis; Carbon nanotubes; Ru nanoparticles; Cinnamaldehyde; Hydrogenation; CHEMICAL-VAPOR-DEPOSITION; RUTHENIUM CATALYSTS; HETEROGENEOUS CATALYSIS; AMMONIA-SYNTHESIS; NANOFIBERS; GENERATION;

D O I：

10.1016/j.catcom.2012.03.035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Uniformly dispersed ruthenium nanoparticles supported on non-functional carbon nanotubes (CNT) have been successfully synthesized by using a facile and solvent-free microwave-assisted thermolytic method with dodecacarbonyltriruthenium as the precursor. The results show that 2-4 mn sized spheres of Ru nanoparticles were uniformly dispersed and supported on non-functional CNT by several minutes' exposure to microwave irradiation without solvent. The Ru/CNT catalysts show the desired conversion of about 80% and selectivity to hydrocinnamaldehyde of about 72% in the selective hydrogenation of cinnamaldehyde, where the catalytic performance has been found to depend on both the Ru loading and the surface properties of CNT. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：65 / 69

页数：5

共 50 条

[1] MICROWAVE-ASSISTED SYNTHESIS AND ENHANCED PHOTOCATALYTIC ACTIVITY OF CARBON NANOTUBES SUPPORTED ZnS NANOPARTICLES
Wan, G.
Wang, G.
JOURNAL OF OPTOELECTRONIC AND BIOMEDICAL MATERIALS, 2015, 7 (04): : 85 - 91
[2] Microwave-assisted synthesis and characterization of bimetallic PtRu alloy nanoparticles supported on carbon nanotubes
Rahsepar, Mansour
Kim, Hasuck
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 649 : 1323 - 1328
[3] Recent Trends in the Microwave-Assisted Synthesis of Metal Oxide Nanoparticles Supported on Carbon Nanotubes and Their Applications
Motshekga, Sarah C.
Pillai, Sreejarani K.
Ray, Suprakas Sinha
Jalama, Kalala
Krause, Rui W. M.
JOURNAL OF NANOMATERIALS, 2012, 2012
[4] Fast Microwave-Assisted Synthesis of Uniform Magnetic Nanoparticles
Kozakova, Z.
Bazant, P.
Machovsky, M.
Babayan, V.
Kuritka, I.
ACTA PHYSICA POLONICA A, 2010, 118 (05) : 948 - 949
[5] Microwave-assisted synthesis of carbon supported Pt nanoparticles for fuel cell applications
Chen, WX
Lee, JY
Liu, ZL
CHEMICAL COMMUNICATIONS, 2002, (21) : 2588 - 2589
[6] Preparation of Pt and PtRu nanoparticles supported on carbon nanotubes by microwave-assisted heating polyol process
Chen, WX
Lee, JY
Liu, ZL
MATERIALS LETTERS, 2004, 58 (25) : 3166 - 3169
[7] Tunable Selective Hydrogenation of Cinnamaldehyde by Capped Pt/Pd Nanoparticles Supported on Carbon Nanotubes
Zhang, Minghui
Wang, Tengda
Zhang, Mingwei
Wang, Qingfa
Wang, Li
Zhang, Xiangwen
Li, Guozhu
CHEMISTRYSELECT, 2022, 7 (15):
[8] Graphene-supported Pd nanoparticles: microwave-assisted synthesis and as microwave-active selective hydrogenation catalysts
Yang, Jing-He
Ma, Ding
RSC ADVANCES, 2013, 3 (26): : 10131 - 10134
[9] Microwave-assisted synthesis of ceria nanoparticles on carbon nanotubes and their dye-removal assesstment
Lopez-Tinoco, Julian
Lara-Romero, Javier
Rangel, Ricardo
Apolinar-Cortes, Jose
Paraguay-Delgado, Francisco
Jimenez-Sandoval, Sergio
Bazan-Diaz, Lourdes
Mendoza-Cruz, Ruben
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2021, 13 : 70 - 82
[10] Microwave-assisted synthesis of Ru/mesoporous carbon composites for supercapacitors
He, Xiaojun
Xie, Kang
Li, Ruchun
Wu, Mingbo
MATERIALS LETTERS, 2014, 115 : 96 - 99

← 1 2 3 4 5 →