Gas-Chromatographic Headspace Analysis: Metrological Aspects

被引:10
|
作者
Vitenberg, A. G. [1 ]
Konopel'ko, L. A. [2 ]
机构
[1] St Petersburg State Univ, Fac Chem, St Petersburg 198504, Russia
[2] Fed State Unitary Enterprise Mendeleev All Russia, St Petersburg 190005, Russia
关键词
gas chromatography; headspace analysis; gas extraction; buffer effect of heterogeneous systems; gas mixtures; vapor-phase sources of gas-vapor mixtures; GASEOUS STANDARD SOLUTIONS; VOLATILE COMPONENTS; PARTITION-COEFFICIENTS; MIXTURES; EXTRACTION; VAPOR; EQUILIBRIUM; CALIBRATION; SYSTEMS; SUBSTANCES;
D O I
10.1134/S106193481103018X
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Various methods are studied for preparing stable gas mixtures with trace amounts of volatile substances based on a buffer effect of heterogeneous systems and implemented into headspace analysis, that is, static and dynamic versions of gas extraction. Information is provided on certified procedures for preparing such mixtures, that is, vapor-phase sources of gas mixtures included into the State Register of Measuring Instruments.
引用
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页码:438 / 457
页数:20
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