Studies on transition metal complexes containing the scorpionate ligand (II) - Synthesis and characterization of zinc and cadmium complexes with scorpionate ligands

被引：0

作者：

Deng, Y ^{[1
]}

Wang, RJ ^{[1
]}

Sun, SQ ^{[1
]}

Feng, YP ^{[1
]}

Deng, TZ ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2001年 / 22卷 / 05期

关键词：

Poly (pyrazolyl) borate; Synthesis; Crystal structure; Hydrotris [3-(p-anisyl) pyrazol-1-yl] borate complex of zinc( II ) chloride;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two scorpionate ligands KTp(An) and KTp(An) were prepared and reacted with MX2(M = Zn, Cd; X = Cl, OAc) affording some new complexes, which were characterized by elemental analysis, IR and H-1 NMR. The single crystal structure of Tp(An)ZnCl has been determined by a four-circle X-ray diffractometer, which shows that the coordination environment about the Zn center is distorted tetrahedral. The crystals are monoclinic, space-group P2(1)/n, with dimensions a = 1.005 5(2) nm, b = 1.689 0(3) nm, c = 1.776 0(4) nm, beta = 102. 16(3)degrees and Z = 4, with final residuals R = 0. 050 0 and wR = 0.120 2.

引用

页码：764 / 767

页数：4

共 15 条

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