Highly dispersed Ni particles on Ru/NiAl catalyst derived from layered double hydroxide for selective CO methanation

被引:27
|
作者
Mohaideen, K. Khaja [1 ]
Kim, Woohyun [1 ]
Koo, Kee Young [1 ]
Yoon, Wang Lai [1 ]
机构
[1] KIER, New & Renewable Energy Res Div, Hydrogen Lab, Taejon 305343, South Korea
关键词
CO selective methanation; CO removal; Nickel; Layered double hydroxides; Ruthenium; Co-precipitation; SUPPORTED RU CATALYSTS; GAS SHIFT REACTION; CARBON-MONOXIDE; METAL-CATALYSTS; FUEL; REMOVAL; HYDROTALCITE; PERFORMANCE; REDUCTION; NI/AL2O3;
D O I
10.1016/j.catcom.2014.10.034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this communication, we report novel Ru/NiAl-layered double hydroxide derived catalysts for CO removal by selective CO methanation. The experimental results revealed that uncalcined Ru/NiAl catalyst shows the fine dispersion of the nickel particles and remarkably high activity to CO at wider operating temperature window ranging from 150 degrees C to 250 degrees C. This work shows promising potential in further application of selective CO methanation as deep CO removal process of fuel processors especially for polymer electrolyte membrane fuel cells (PEMFC). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:8 / 13
页数:6
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