Preparation and molecular structure of [(η5-C5H5)Fe(CO)2(η1-PhNO2)]BF4

被引：11
|
作者：
Srivastava, RS
Khan, MA
Nicholas, KM
机构：
[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
[2] Univ SW Louisiana, Dept Chem & Biochem, Lafayette, LA 70504 USA
来源：
INORGANICA CHIMICA ACTA | 2003年 / 349卷
基金：
美国国家科学基金会;
关键词：
crystal structures; iron complexes; carbonyl complexes; cyclopentadienyl complexes; nitrobenzene complexes;
D O I：
10.1016/S0020-1693(03)00059-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The nitrobenzene complex [(eta(5)-C5H5)Fe(CO)(2)(PhNO2)]BF4 (1) has been prepared by the reaction of CpFe(CO)(2)I with AgBF4 in the presence of nitrobenzene. Characterization by X-ray diffraction reveals that complex 1.1/2(CH2Cl2) has a nearly planar PhNO2 ligand coordinated in the eta(1)-O mode. Reactivity studies indicate that I is not a primary intermediate in the allylic amination of olefins by nitroarenes which are catalyzed by [CpFe(CO)(2)](2). (C) 2003 Elsevier Science B.V. All rights reserved.
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页码：269 / 272
页数：4
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