Two-Coordinate Transition-Metal Centers With Metal-Metal Bonds

被引：8
|
作者：
Holland, Patrick L. [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 28期
关键词：
electron-deficient compounds; iron; low-coordinate metals; metal-metal interactions; xenophilic complexes; COMPLEXES; REACTIVITY; LIGANDS; CHEMISTRY; IRON(II); CLUSTERS;
D O I：
10.1002/anie.201101209
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
M-M bonds meet two-coordination: Systems with metal-metal bonds are of great interest in inorganic chemistry. A recent report describes the first example of a metal-metal bond to a two-coordinate transition-metal center (see structure, Fe orange, O red, C gray). The metal-metal bond in this "xenophilic complex" is best described as a dative bond. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6213 / 6214
页数：2
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