A New Rare-Earth Metal Coordination Polymer Constructed from N-hetero Aromatic Multicarboxylate Ligand

被引：6

作者：

Dong, Hai-Jun ^{[1
]}

Wang, Min ^{[1
]}

Huang, Shu-Wei ^{[1
]}

Wu, Yan-Ling ^{[1
]}

Li, Hao-Hong ^{[1
]}

Chen, Zhi-Rong ^{[1
]}

机构：

[1] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2010年 / 21卷 / 04期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

Aromatic carboxylate; Gd complex; Co-ordination polymer; CRYSTAL-STRUCTURE; LANTHANIDE; CHAINS; COMPLEXES; CLUSTERS; IONS;

D O I：

10.1007/s10876-010-0344-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of Gd(NO3)(3)center dot 6H(2)O with 2,2'-bipyridyl-4,4'-dicarboxylic acid(H2BPDC) ligand results in the formation of a new Gd(III) polymer: {[Gd-2(BPDC)(3)(H2O)(3)]center dot H2O} (n..)(1). The central gadolinium ion is coordinated by eight oxygen atoms to give a dicapped triangular prism geometry. Based on the versatile coordination modes of BPDC2- ligand, together with hydrogen bonds and pi center dot center dot center dot pi stacking interactions, a 3-D network is presented. DFT calculation was executed to probe the electronic structure of 1.

引用

页码：825 / 835

页数：11

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