Nickel catalyzed dealkoxylative Csp2-Csp3 cross coupling reactions - stereospecific synthesis of allylsilanes from enol ethers

被引：59
|
作者：
Guo, Lin [1 ]
Leiendecker, Matthias [1 ]
Hsiao, Chien-Chi [1 ]
Baumann, Christoph [1 ]
Rueping, Magnus [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 10期
关键词：
C-O BONDS; GRIGNARD-REAGENTS; ARYL ETHERS; ENANTIOSELECTIVE ADDITION; STEREOSELECTIVE-SYNTHESIS; PRACTICAL SYNTHESIS; ALLYLATION; EFFICIENT; ALDEHYDES; DERIVATIVES;
D O I：
10.1039/c4cc08187k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The application of cyclic and acyclic enol ethers as electrophiles in cross coupling reactions offers new possibilities for the preparation of functional compounds. A novel nickel catalyzed dealkoxylative cross coupling reaction allows access to structurally diverse allylsilanes and alcohol derivatives with high stereospecificity and in good yields under mild reaction conditions directly from the corresponding enol ethers.
引用
收藏
页码：1937 / 1940
页数：4
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