A reversible metal-ligand bond break associated to a spin-crossover

被引：64
|
作者：
Guionneau, Philippe [1 ]
Le Gac, Frederic [1 ]
Kaiba, Abdellah [1 ]
Costa, Jose Sanchez [1 ]
Chasseau, Daniel [1 ]
Letard, Jean-Francois [1 ]
机构：
[1] Univ Bordeaux 1, CNRS, ICMCB, F-33608 Pessac, France
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 36期
关键词：
D O I：
10.1039/b707836f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The [(FeL)-L-II(CN)(2)]center dot H2O complex,dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1] octadeca-1(18), 2,12,14,16-pentaene]iron(II) monohydrate, exhibits a thermal induced metal-ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta- coordinate high spin state to a hexa-coordinate low spin state.
引用
收藏
页码：3723 / 3725
页数：3
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