Electrochemical behaviour of molybdenum(VI) and tungsten(VI) oxoanions and high-temperature electrochemical synthesis of molybdenum and tungsten carbides

被引：0

作者：

Malyshev, VV ^{[1
]}

Finadorin, AE ^{[1
]}

Novoselova, IA ^{[1
]}

Shapoval, VI ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Gen & Inorgan Chem, Kiev, Ukraine

来源：

CHEMICAL PAPERS-CHEMICKE ZVESTI | 1998年 / 52卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The possibility of realizing multielectron processes of tungsten electroreduction from dimeric forms in the narrow potential range and of controlling process potential by means of melt acid-base properties is shown. Conditions of bringing together the reduction potentials of carbon dioxide and dimeric forms have been found. It has been shown that the direct electrochemical synthesis of molybdenum and tungsten carbides under excessive carbon dioxide pressure is possible in principle.

引用

页码：89 / 95

页数：7

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