Efficient aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds using nickel complexes of air-stable phosphine oxides

被引：225
|
作者：
Ackermann, L [1 ]
Born, R [1 ]
Spatz, JH [1 ]
Meyer, D [1 ]
机构：
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 44期
关键词：
D O I：
10.1002/anie.200501860
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) A couple of couplings: Air-stable diamino-and dioxophosphine oxides are used as preligands in the nickel-catalyzed Kumada cross-coupling reactions of aryl Grignard reagents. A sterically hindered preligand allows for highly efficient cross-coupling of aryl fluorides at ambient temperature (acac = acetylacetonate). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7216 / 7219
页数：4
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