A Nanoscale Multiresponsive Luminescent Sensor Based on a Terbium(III) Metal-Organic Framework

被引：31
|
作者：
Dang, Song [1 ]
Wang, Ting [1 ]
Yi, Feiyan [1 ]
Liu, Qinghui [2 ]
Yang, Weiting [1 ]
Sun, Zhong-Ming [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Jilin Univ, Coll Phys, Changchun 130012, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2015年 / 10卷 / 08期
关键词：
lanthanides; luminescence; metal-organic frameworks; nanostructures; sensors; LANTHANIDE COORDINATION POLYMERS; SINGLE-CRYSTAL TRANSFORMATION; FLUORESCENT-PROBE; FE3+; ENCAPSULATION; RECOGNITION; MODULATION; SEPARATION; POROSITY; HYBRID;
D O I：
10.1002/asia.201500249
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nanoscale terbium-containing metal-organic framework (nTbL), with a layer-like structure and [H2NMe2](+) cations located in the framework channels, was synthesized under hydrothermal conditions. The structure of the as-prepared sample was systematically confirmed by powder XRD and elemental analysis; the morphology was characterized by field-emission SEM and TEM. The photoluminescence studies revealed that rod-like nTbL exhibited bright-green emission, corresponding to (D4FJ)-D-5-F-7 (J=6-3) transitions of the Tb3+ ion under excitation. Further sensing measurements revealed that as-prepared nTbL could be utilized as a multiresponsive luminescent sensor, which showed significant and exclusive detection ability for Fe3+ ions and phenylmethanol. These results highlight the practical applications of lanthanide-containing metal-organic frameworks as fluorescent probes.
引用
收藏
页码：1703 / 1709
页数：7
相关论文
共 50 条
  • [1] Multiresponsive luminescent metal-organic framework for cooking oil adulteration detection and gallium(III) sensing
    Pavlov, Dmitry I.
    Yu, Xiaolin
    Ryadun, Alexey A.
    Samsonenko, Denis G.
    Dorovatovskii, Pavel V.
    Lazarenko, Vladimir A.
    Sun, Na
    Sun, Yaguang
    Fedin, Vladimir P.
    Potapov, Andrei S.
    [J]. FOOD CHEMISTRY, 2024, 445
  • [2] Ultra-low limit of luminescent detection of gossypol by terbium(III)-based metal-organic framework
    Yu, Xiaolin
    Ryadun, Alexey A.
    Potapov, Andrei S.
    Fedin, Vladimir P.
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2023, 452
  • [3] A Novel Magnesium Metal-Organic Framework as a Multiresponsive Luminescent Sensor for Fe(III) Ions, Pesticides, and Antibiotics with High Selectivity and Sensitivity
    Xu, Ning
    Zhang, Qinghua
    Hou, Baoshan
    Cheng, Qian
    Zhang, Guoan
    [J]. INORGANIC CHEMISTRY, 2018, 57 (21) : 13330 - 13340
  • [4] A stable terbium(III) metal-organic framework as a dual luminescent sensor for MnO4- ions and nitroaromatic explosives
    Zhang, Guoshuai
    Wu, Guihong
    Zhang, Hong
    Wang, Guannan
    Han, Haitao
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2021, 295
  • [5] Stable CdII-Based Metal-Organic Framework as a Multiresponsive Luminescent Sensor for Acetylacetone, Salicylaldehyde, and Benzaldehyde with High Sensitivity and Selectivity
    Zhang, Rui-Jie
    Wang, Jin-Jin
    Xu, Hui
    Zhu, Zi-Hao
    Zheng, Teng-Fei
    Peng, Yan
    Chen, Jing-Lin
    Liu, Sui-Jun
    Wen, He-Rui
    [J]. CRYSTAL GROWTH & DESIGN, 2023, 23 (08) : 5564 - 5570
  • [6] A luminescent nanoscale metal-organic framework for sensing of nitroaromatic explosives
    Xu, Hui
    Liu, Fu
    Cui, Yuanjing
    Chen, Banglin
    Qian, Guodong
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (11) : 3153 - 3155
  • [7] Utilizing a water-stable terbium (III) metal-organic framework for luminescent sensing of nitroimidazole antibiotics
    Han, Haitao
    Du, Xiaoxue
    Wang, Shun
    Yao, Liyi
    Zhang, Guoshuai
    Wang, Mengke
    [J]. POLYHEDRON, 2024, 259
  • [8] A luminescent Eu(III)-based metal-organic framework as a highly effective sensor for cation and anion detections
    Wang, Qiu-Shuang
    Li, Jia-Jia
    Zhang, Mei-Na
    Li, Xia
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2018, 258 : 358 - 364
  • [9] A ketone functionalized luminescent terbium metal-organic framework for sensing of small molecules
    Guo, Zhiyong
    Song, Xuezhi
    Lei, Huaping
    Wang, Hailong
    Su, Shengqun
    Xu, Hui
    Qian, Guodong
    Zhang, Hongjie
    Chen, Banglin
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (02) : 376 - 379
  • [10] An efficient strategy for improving the luminescent sensing performance of a terbium(iii) metal-organic framework towards multiple substances
    Wang, Xiaoning
    Li, Jia-Luo
    Jiang, Chenggang
    Hu, Peng
    Li, Bao
    Zhang, Tianle
    Zhou, Hong-Cai
    [J]. CHEMICAL COMMUNICATIONS, 2018, 54 (94) : 13271 - 13274
12345