Triangular Silver Nanoplates as a Spectrophotometric Reagent for the Determination of Mercury(II)

被引：19

作者：

Furletov, A. A. ^{[1
]}

Apyari, V. V. ^{[1
]}

Garshev, A. V. ^{[1
,2
]}

Dmitrienko, S. G. ^{[1
]}

Zolotov, Yu. A. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Mat Sci, Moscow 119991, Russia

来源：

JOURNAL OF ANALYTICAL CHEMISTRY | 2017年 / 72卷 / 12期

基金：

俄罗斯科学基金会;

关键词：

silver nanoparticles; triangular silver nanoplates; mercury(II); spectrophotometry; surface plasmon resonance; COLORIMETRIC VISUALIZATION; SODIUM THIOSULFATE; RAPID METHOD; URIC-ACID; NANOPARTICLES; NANOPRISMS; REDUCTION; IODIDE; SERUM; GOLD;

D O I：

10.1134/S1061934817120061

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The applicability of triangular silver nanoplates (TNPs) as a spectrophotometric reagent for the determination of mercury(II) in an aqueous solution was estimated. The method is based on the oxidation of TNPs with a mean edge length of 52 nm and thickness of 4 nm by mercury(II) ions, which is accompanied by a decrease in the surface plasmon resonance of nanoparticles. The effect of reaction time, pH of solution, and TNP concentration on the sensitivity of mercury(II) determination was studied. The limit of mercury(II) detection under the selected conditions was 0.022 mu g/mL.

引用

页码：1203 / 1207

页数：5

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