Enthalpies of solution of 1-ethyl-3-methyl-imidazolium chloride and aluminum chloride in molten chloroaluminate ionic liquids

被引：11
|
作者：
Keil, Philipp [1 ]
Koenig, Axel [1 ]
机构：
[1] Univ Erlangen Nurnberg, Chair Separat Sci & Technol, Erlangen, Germany
来源：
THERMOCHIMICA ACTA | 2011年 / 524卷 / 1-2期
关键词：
Enthalpies of solution; Ionic liquids; Chloroaluminate melts; Aluminum chloride; Solution calorimetry; ELECTRODEPOSITION; SPECTROSCOPY; SYSTEM; MELTS;
D O I：
10.1016/j.tca.2011.07.006
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Enthalpies of solution of 1-ethyl-3-methyl-imidazolium chloride and anhydrous aluminum chloride in molten mixtures of both substances were determined. Measurements were done at T = 323.15 K varying the aluminum chloride content of the melt in the mole fraction range 0.23 < x(AlCl(3)) < 0.58. Enthalpies of solution of aluminum chloride were measured additionally at T = 363.15 K in the mole fraction range 0 < x(AlCl(3)) < 0.46 with the aim to evaluate the temperature dependence of the enthalpy of solution of AlCl(3). (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：202 / 204
页数：3
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