Synthetic potential of the reaction of allylic phosphonium ylides with α,β-unsaturated carbonyl compounds

被引：5

作者：

Schneider, DF ^{[1
]}

Venter, AC ^{[1
]}

机构：

[1] Univ Stellenbosch, Dept Chem, ZA-7600 Stellenbosch, South Africa

来源：

SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 08期

关键词：

D O I：

10.1080/00397919908086106

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of triphenylphosphonium-2-propenylide (14) with mesityl oxide (9) is shown to proceed via initial Michael addition followed by transylidation and an intramolecular Wittig condensation to yield I,5,5-trimethyl-1,3-cyclohexadiene (10) as the reaction product.

引用

页码：1303 / 1315

页数：13

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