Nd[Al(iPrO)4]3, a novel tetranuclear alkoxide forming merohedrally twinned crystals

被引:7
|
作者
Moustiakimov, M [1 ]
Kritikos, M
Westin, G
机构
[1] Stockholm Univ, Arrhenius Lab, S-10691 Stockholm, Sweden
[2] Uppsala Univ, Angstrom Lab, S-75121 Uppsala, Sweden
关键词
D O I
10.1107/S0108270101000750
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new tetranuclear alkoxide hexa-mu (2)-isopropoxy-1:2 kappa O-4;1:3 kappa O-4;1:4 kappa (4) O-hexaisopropoxy-2 kappa O-2,3 kappa O-2,4 kappa O-2-trialuminium(III)neodymium(III), [Nd{Al(C3H7O)(4)}(3)], has a metal-oxygen NdAl3O12 core which consists of four metal atoms arranged in an approximately planar triangular geometry. The central Nd atom is six-coordinated by O atoms and the Al atoms are four-coordinated by O atoms.
引用
收藏
页码:515 / 516
页数:2
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