Polysulfide Coordination Clusters of the Lanthanides

被引：35

作者：

Ma, Ying-Zhao ^{[1
]}

Bestgen, Sebastian ^{[1
]}

Gamer, Michael T. ^{[1
]}

Konchenko, Sergey N. ^{[1
,2
,3
]}

Roesky, Peter W. ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Inorgan Chem, Engesserstr 15, D-76131 Karlsruhe, Germany

[2] SB RAS, Nikolaev Inst Inorgan Chem, Prosp Lavrentieva 3, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 43期

基金：

俄罗斯科学基金会;

关键词：

coordination clusters; lanthanides; samarium; sulfur; ytterbium; RARE-EARTH-ELEMENTS; STERIC BULK; REACTIVITY; COMPLEXES; SULFUR; ACTIVATION; LIGANDS; TRANSFORMATIONS; PHOSPHORUS; PRECURSORS;

D O I：

10.1002/anie.201707578

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [(DippForm)(2)Ln(thf)(2)] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)(3)Ln(3)S(12)] (Ln = Sm, Yb; DippForm = N,N'-bis(2,6-diisopropylphenyl)formamidinate). These are the first felement coordination clusters (Ln(n)S(x)) with a larger polysulfide unit (n and x > 2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S-8 with divalent lanthanides.

引用

页码：13249 / 13252

页数：4

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