N,N-Bis(2-bromobenzyl)-2,6-diisopropyl-aniline

被引:1
|
作者
Comsa, Carmen [1 ]
Silvestru, Cristian [1 ]
Varga, Richard A. [1 ]
机构
[1] Univ Babes Bolyai, Fac Chem & Chem Engn, RO-400028 Cluj Napoca, Romania
关键词
D O I
10.1107/S160053680705670X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of the title compound, C26H29Br2N, contains two independent molecules in the asymmetric unit. In molecule A, one benzyl group is involved in an intramolecular C-H center dot center dot center dot benzene contact. Molecules A are linked by intermolecular C-H center dot center dot center dot benzene contacts involving the aniline ring into a one-dimensional association along the c axis. Molecules B form a different array along the a axis, viz. dimeric units based on intermolecular C-H center dot center dot center dot benzene contacts involving one benzyl aromatic ring; they are further linked through C-H center dot center dot center dot benzene contacts involving the second benzyl aromatic ring. In the crystal structure, supramolecular arrays of the same type are arranged in layers stacked alternately along the b axis, with no interactions between the layers.
引用
收藏
页码:O4714 / U5099
页数:18
相关论文
共 50 条
  • [1] N-(2-Bromobenzyl)-2,6-diisopropylaniline
    Cristea, Adina
    Varga, Richard A.
    Silvestru, Cristian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4528 - U3377
  • [2] Isotypic crystal structures of 2,6-dibromo-N,N-bis(4-nitrophenyl)aniline and 2,6-dichloro-N,N-bis(4-nitrophenyl)aniline
    Kautny, Paul
    Froehlich, Johannes
    Stoeger, Berthold
    Weil, Matthias
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2014, 70 : 65 - +
  • [3] N,N-Bis(2-bromoethyl)aniline
    Bojan, R. Vilma
    Varga, Richard A.
    Silvestru, Cristian
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O86 - U3283
  • [4] N,N-Bis(2-pyridylmethyl)aniline
    Kang, Jun-Tao
    Wang, Guan-Hua
    Xu, Jing-Wei
    Yang, Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O475 - U3494
  • [5] Bis(2-bromobenzyl) trisulfide
    Singh, Suneel. P.
    Lough, Alan. J.
    Schwan, Adrian. L.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O361 - U2491
  • [6] N-(2-Bromobenzyl)cinchoninium bromide
    Skorska-Stania, Agnieszka
    Jezierska-Zieba, Magdalena
    Kakol, Barbara
    Fedorynski, Michal
    Oleksyn, Barbara J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2803 - +
  • [7] Bis(2-bromobenzyl) ether
    Anuradha, Venkatramu
    Nagendra, P.
    Kumar, S. Madan
    Siddaraju, B. P.
    Lokanath, N. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 0765 - +
  • [8] N,N-Bis(trifluoromethylsulfonyl)aniline
    Bats, JW
    Weyrauch, JP
    Hashmi, ASK
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : O590 - O591
  • [9] N,N-Bis[2-(2-furyl)-2-(hydroxyimino)ethyl]aniline
    Gueven, Oezden Oezel
    Caylak, Nagihan
    Hoekelek, Tuncer
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O3827 - U3187
  • [10] Airborne occupational allergic contact dermatitis from N,N-bis[2-bromo-ethyl] aniline and N,N-bis [2-[(methylsulfonyl)-oxy]ethyl]aniline in a chemistry student
    Verlinden, V
    Gloossens, A
    CONTACT DERMATITIS, 2003, 49 (03) : 169 - 169