Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes

被引：32
|
作者：
Nishimura, Takahiro [1 ]
Sawano, Takahiro [1 ]
Tokuji, Sumito [1 ]
Hayashi, Tamio [1 ]
机构：
[1] Kyoto Univ, Dept Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 36期
关键词：
ENANTIOSELECTIVE MICHAEL ADDITION; DOPAMINE BETA-HYDROXYLASE; TERMINAL ALKYNES; 1,3-DICARBONYL COMPOUNDS; CARBONYL GROUPS; ATOM ECONOMY; KETONES; 1,4-ADDITION; NITROOLEFINS; ALDEHYDES;
D O I：
10.1039/c0cc02181d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Asymmetric addition of (triisopropylsilyl)acetylene to nitroalkenes took place in the presence of a rhodium/chiral bisphosphine catalyst to give beta-alkynylated nitroalkanes in high yields with high enantioselectivity.
引用
收藏
页码：6837 / 6839
页数：3
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