Structure and mechanical behaviors of thermoplastic polyurethane thin film coated polyamide 6 fibers part II. A solution coating method

被引:7
|
作者
John, Baiju [1 ]
Furukawa, Mutsuhisa [1 ,2 ]
机构
[1] Nagasaki Univ, Grad Sch Sci & Technol, Div Mat Sci, Nagasaki 8528521, Japan
[2] Nagasaki Univ, Nagasaki Inst Polyurethane Sci & Technol, Chuo Ku, Fukuoka 8100035, Japan
关键词
Thermoplastic polyurethane; Thin film coating; Polyamide; 6; fiber; Interface interaction; Micro-cracks; Abrasion; MICROPHASE-SEPARATED STRUCTURE; CRYSTAL-STRUCTURE; NYLON-6; ELASTOMERS; DIISOCYANATE; POLYMORPHISM; PREDICTION; THICKNESS; LACTAMS; GLYCOL;
D O I
10.1007/s10965-011-9764-6
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Thermoplastic polyurethane thin film (TPU) coated PA6 fibers were prepared by dipping fibers into a TPU solution. The thickness of the thin film coating was 20 mu m. A series of polymer glycols which include polycarbonate, polyether and polyester were used for the preparation of the TPU. Both tensile strength and elongation at break of the TPU coated fibers increased although both magnitudes of the TPUs are much lower than for the original PA6 fibers. Also there was a significant improvement in the abrasion resistance TPU coated PA6 fibers. The PA6 fibers are prone to micro-cracks when under mechanical stress but the TPU thin film coating delayed the formation of the micro-cracks, thereby improving the mechanical properties of PA6 fibers. The theoretical investigation on the effect of interface interaction region using the viscous flow model described could clearly explain the effect of the same on the mechanical performance of TPU coated PA6 fibers.
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页数:12
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