Electroviscous effect of moderately concentrated colloidal suspensions under overlapping conditions

被引:16
|
作者
Ruiz-Reina, E
García-Sánchez, P
Carrique, F
机构
[1] Univ Malaga, Dept Fis Aplicada 2, E-29071 Malaga, Spain
[2] Univ Seville, Dept Elect & Electromagnetismo, E-41012 Seville, Spain
[3] Univ Malaga, Dept Fis Aplicada 1, E-29071 Malaga, Spain
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2005年 / 109卷 / 11期
关键词
D O I
10.1021/jp044619p
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work we present a theoretical model for the calculation of the electroviscous coefficient of a colloidal suspension. The treatment is not limited for dilute suspensions and includes the contribution of the overlapping between adjacent ionic layers. The development here used is based on a cell model, which is applicable to Newtonian suspensions under low shear conditions and without crystalline ordering. Also presented are a complete study of the new numerical results and comparisons with previous results. We find new behaviors for the case of moderate volume fractions that do not appear in the dilute limit.
引用
收藏
页码:5289 / 5299
页数:11
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