2-Nitrodiene 1 reacted with 3-mercapto-1,2,4-triazole and cyclohexyl thiol to yield compounds 3 and4, respectively. Compounds 7a-d were obtained by reactions of 6a-d with 2. The novel N,S-substituted dienes 9a-c were obtained by treatment of compound 6b with the piperazine derivatives 8a-c. Compound 6b was reacted with 10 to give compound 11 as a new morpholine derivative. Compound 6b gave a new monobutadienyl homopiperazine 13 when reacted with homopiperazine in methylene chloride. Compound 4 was structurally characterized by single-crystal X-ray diffraction.
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Istanbul Univ, Dept Chem, Fac Engn, Div Organ Chem, TR-34320 Istanbul, TurkeyIstanbul Univ, Dept Chem, Fac Engn, Div Organ Chem, TR-34320 Istanbul, Turkey
Ibis, Cemil
Gokmen, Zeliha
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Istanbul Univ, Dept Chem, Fac Engn, Div Organ Chem, TR-34320 Istanbul, TurkeyIstanbul Univ, Dept Chem, Fac Engn, Div Organ Chem, TR-34320 Istanbul, Turkey
Gokmen, Zeliha
Cetin, Zerrin
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Istanbul Univ, Dept Chem, Fac Engn, Div Organ Chem, TR-34320 Istanbul, TurkeyIstanbul Univ, Dept Chem, Fac Engn, Div Organ Chem, TR-34320 Istanbul, Turkey