Mechanism and efficiency of the inhibiting action of 1,3-di-(4-phenylaminophenoxy)-2-propanol and 2,6-di-tert-butyl-4-methylphenol in the oxidation of methyl linoleate

被引：0
|
作者：
Pis'menskii, AV [1 ]
Psikha, BL [1 ]
Kharitonov, VV [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
来源：
PETROLEUM CHEMISTRY | 2001年 / 41卷 / 05期
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D O I：
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The mechanism of the inhibiting action of the aromatic amine 1,3-di-(4-phenylaminophenoxy)-2-propanol and the sterically hindered phenol 2,6-di-tert-butyl-4-methylphenol (ionol) in oxidizing methyl linoleate was studied. The key reactions in the mechanism of inhibition by the antioxidants were identified, and the corresponding kinetic parameters were estimated. The mechanisms of the action of the antioxidants were compared, and the reasons for the main differences in their efficiency were established.
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页码：346 / 351
页数：6
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