Effect of mechanical activation on the physicochemical properties of MoO3

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作者
Poluboyarov, VA [1 ]
Kiselevich, SN [1 ]
Kirichenko, OA [1 ]
Pauli, IA [1 ]
Korotaeva, ZA [1 ]
Dektyarev, SP [1 ]
Ancharov, AI [1 ]
机构
[1] Russian Acad Sci, Inst Solid State Chem & Mineral Proc, Siberian Div, Novosibirsk 630091, Russia
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T [工业技术];
学科分类号
08 ;
摘要
The effect of mechanical activation on the sintering behavior and strength of MoO3 was studied. Mechanical activation of MoO3 powder was found to produce particles similar or equal to 10 nm in size, whose number amounts to 50% of the total number of particles, whereas the weight does not exceed 5%. EPR, IR, synchrotron XRD, and EXAFS data demonstrate that the 70-nm fraction of the MoO3 powder, including similar or equal to 10-nm particles, consists of defect-free orthorhombic MoO3 and crystallographic-shear structures.
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页码:1152 / 1158
页数:7
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