Copper(I) pseudohalide complexes with 4,6-dimethylpyrimidine-2(1H)-thione and triphenylphosphane as ligands.: The X-ray crystal structures of [Cu(N3)(dmpymtH)(PPh3)2] and [Cu(NCS)(dmpymtH)(PPh3)2]

被引：19

作者：

Lemos, SS ^{[1
]}

Camargo, MA

Cardoso, ZZ

Deflon, VM

Försterling, FH

Hagenbach, A

机构：

[1] Univ Brasilia, Inst Quim, BR-70919970 Brasilia, DF, Brazil

[2] Univ Wisconsin, Dept Chem, Milwaukee, WI 53211 USA

[3] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

来源：

POLYHEDRON | 2001年 / 20卷 / 9-10期

关键词：

synthesis; copper(I) complexes; pseudohalides; crystal structures; dimethylpyrimidenethione; NMR spectroscopy;

D O I：

10.1016/S0277-5387(01)00701-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of mixed-ligand copper(I) coordination compounds containing pseudohalides (azide and thiocyanate), 4,6-dimethylpyrimidine-2(1H)-thione (dmpymtH), and triphenylphosphane is described. The crystalline and molecular structure of [Cu(N-3)(dmpymtH)(PPh3)(2)] (2) and [Cu(NCS)(dmpymtH)(PPh3)(2)] (3) have been determined by X-ray diffraction methods. The copper atom has a tetra-coordinate CuNP2S chromophore with distorted tetrahedral coordination in both complexes. Vibrational and H-1, C-13, P-31 NMR spectra of the complexes are discussed and related to the structures. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：849 / 854

页数：6

共 50 条

[1] Synthesis and characterization of [Cu(Phca2en)(PPh3)X] (X=Cl, Br, I, NCS, N3) complexes:: crystal structures of [Cu(Phca2en)(PPh3)Br] and [Cu(Phca2en)(PPh3)I]
Dehghanpour, Saeed
Mahmoudkhani, Amir H.
Amirnasr, Mehdi
[J]. STRUCTURAL CHEMISTRY, 2006, 17 (03) : 255 - 262
[2] Synthesis and characterization of [Cu(Phca2en)(PPh3)X] (X=Cl, Br, I, NCS, N3) complexes: crystal structures of [Cu(Phca2en)(PPh3)Br] and [Cu(Phca2en)(PPh3)I]
Saeed Dehghanpour
Amir H. Mahmoudkhani
Mehdi Amirnasr
[J]. Structural Chemistry, 2006, 17 : 255 - 262
[3] Preparation and crystal structures of Ag[N(CN)2](PPh3)2, Cu[N(CN)2](PPh3)2, and Ag[N(CN)2](PPh3)3
Bessler, KE
Romualdo, LL
Deflon, VM
Hagenbach, A
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (09): : 1942 - 1945
[4] Synthesis, characterization, and crystal structures of [Cu(ca2en)(PPh3)(X)](X = Cl, Br, I, NCS, N3) complexes
Kickelbick, G
Amirnasr, M
Khalaji, AD
Dehghanpour, S
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2003, 56 (04) : 323 - 328
[5] BIS(TRIPHENYLPHOSPHINE)COPPER(I) DERIVATIVES OF SUBSTITUTED ARACHNO 9-VERTEX BORANE ANIONS, CU(PPH3)2(B9H13H), CU(PPH3)2(B9H13NCS), CU(PPH3)2(B9H13NCSE), CU(PPH3)2(B9H13NCBPH3), CU(PPH3)2(B9H13NCBH3), CU(PPH3)2(B9H13H), CU(PPH3)2(B9H13NCBH2NCBH3)
MEINA, DG
MORRIS, JH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (09): : 1903 - 1907
[6] NEW COPPER(I) CHLORIDE COMPLEXES WITH HETEROCYCLIC THIONES AND TRIPHENYLPHOSPHINE AS LIGANDS - CRYSTAL-STRUCTURES OF [CU(PPH3)2(BZIMTH2)CL].CH3COCH3 AND [CU(PPH3)2(NBZIMTH2)CL]
SKOULIKA, S
AUBRY, A
KARAGIANIDIS, P
ASLANIDIS, P
PAPASTEFANOU, S
[J]. INORGANICA CHIMICA ACTA, 1991, 183 (02) : 207 - 211
[7] Crystal and molecular structure of copper( I ) complex [Cu(PPh3)2(NO3)]
Yang, RN
Li, TX
Sun, YA
Hu, XY
Jin, DM
Luo, BS
[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (02) : 126 - 130
[8] Syntheses and crystal structures of linear coordinated complexes of Ag+ with the ligands C(PPh3)2 and (HC{PPh3}2)+
Petz, Wolfgang
Oexler, Florian
Neumueller, Bernhard
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (25) : 4094 - 4099
[9] 4-COORDINATE COPPER(I) IODIDE COMPLEXES WITH TRIPHENYLPHOSPHINE AND HETEROCYCLIC THIONE LIGANDS - THE CRYSTAL-STRUCTURE OF [CU(PPH3)2(PYMTH)I]
ASLANIDIS, P
HADJIKAKOU, SK
KARAGIANNIDIS, P
GDANIEC, M
KOSTURKIEWICZ, Z
[J]. POLYHEDRON, 1993, 12 (18) : 2221 - 2226
[10] REACTIVITY OF COPPER(I) TETRAHYDROBORATES TOWARD CS2 AND SCNPH - STRUCTURES OF "(PPH3)2CU(MU-S2CSCH2SCS2)CU(PPH3)2, (PPH3)2CU(S2COET), AND (PPH3)2CU(S2CNHPH).CHCL3
BIANCHINI, C
GHILARDI, CA
MELI, A
MIDOLLINI, S
ORLANDINI, A
[J]. INORGANIC CHEMISTRY, 1985, 24 (06) : 932 - 939

← 1 2 3 4 5 →