Synthesis of natural products containing highly strained trans-fused bicyclo[3.3.0]octane: historical overview and future prospects

被引：19

作者：

Zhang, Wen ^{[1
,2
]}

Li, Lingzi ^{[1
,2
]}

Li, Chuang-Chuang ^{[1
]}

机构：

[1] Southern Univ Sci & Technol SUSTech, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China

[2] Southern Univ Sci & Technol SUSTech, Guangdong Prov Key Lab Catalysis, Dept Chem, Shenzhen 518055, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2021年 / 50卷 / 17期

基金：

中国国家自然科学基金;

关键词：

ENANTIOSELECTIVE TOTAL-SYNTHESIS; ALKOXY-DIRECTED CYCLIZATION; BIOLOGICAL EVALUATION; CORE; SESQUITERPENES; EPOXYDICTYMENE; REARRANGEMENT; PALAUAMINE; DITERPENE; DYNEMICIN;

D O I：

10.1039/d0cs01471k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Owing to high strain energy, molecules with trans-fused bicyclo[3.3.0]octane ring systems are very difficult to synthesize, and there are very few approaches to access them. Recently, a number of natural products with such ring systems have been made by the synthetic community. However, there has been no review in this field before. This review provides a systematic and comprehensive discussion on the synthesis of natural products containing trans-fused bicyclo[3.3.0]octanes and the historical context of this work. The prospects for future research in this field are also discussed. Covering the literature before 2021, this review aims to offer a helpful reference for total synthesis of highly strained natural products containing trans-fused bicyclo[3.3.0]octane ring systems.

引用

页码：9430 / 9442

页数：13

共 9 条

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