Chain compounds of rhodium(II) trifluoroacetate linked by p-quinone [Rh-2(O2CCF3)(4)(p-Q)](n), p-Q=1,4-benzoquinone, 1,4-naphthoquinone, and 2,3-dimethyl-1,4-benzoquinone

被引：26

作者：

Handa, M ^{[1
]}

Mikuriya, M ^{[1
]}

Sato, Y ^{[1
]}

Kotera, T ^{[1
]}

Nukada, R ^{[1
]}

Yoshioka, D ^{[1
]}

Kasuga, K ^{[1
]}

机构：

[1] KWANSEI GAKUIN UNIV, SCH SCI, DEPT CHEM, NISHINOMIYA, HYOGO 662, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1996年 / 69卷 / 12期

关键词：

D O I：

10.1246/bcsj.69.3483

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of chain complexes of rhodium(II) trifluoroacetate, [Rh-2(O2CCF3)(4)(P-Q)](n) (P-Q=1,4-benzoquinone (1,4-bq), 1,4-naphthoquinone (1,4-nq), and 2,3-dimethyl-1,4-benzoquinone (2,3-dmbq)) have been prepared. The chain structures were confirmed by the X-ray structure analyses. The carbonyl oxygens of the p-quinones are coordinated to the Rh-2 centers with the distances of 2.248(5) (for p-Q=1,4-bq), 2.248(3) (for p-Q=1,4-nq), and 2.247(9) Angstrom (for p-Q=2,3-dmbq), respectively. The bridging mode of the p-quinone was discussed in relation to the substituent effect of CS group on the carboxylate.

引用

页码：3483 / 3488

页数：6

共 27 条

[1] Chain complexes of rhodium(II) pivalate dimers formed by ligation of C=C double bond and carbonyl oxygen of p-quinone [{Rh2(O2CCMe3)4(p-Q)2}{Rh2(O2CCMe3)4}]n, p-Q = 1,4-benzoquinone and 1,4-naphthoquinone
Handa, M
Nakao, T
Mikuriya, M
Kotera, T
Nukada, R
Kasuga, K
INORGANIC CHEMISTRY, 1998, 37 (01) : 149 - 152
[2] Chain Complexes of Rhodium(II) Pivalate Dimers Formed by Ligation of C=C Double Bond and Carbonyl Oxygen of p-Quinone [{Rh2(O2CCMe3)4(p-Q)2}{ @Rh2(O 2CCMe3)4}]n, p-Q = 1,4-Benzoquinone and 1,4-Naphthoquinone
Handa, M.
Nakao, T.
Mikuriya, M.
Kotera, T.
Inorganic Chemistry, 37 (01):
[3] Chain compounds of molybdenum(II) trifluoroacetate linked by p-quinones [Mo2(O2CCF3)4(p-quin)]n, p-quin = 9,10-anthraquinone, 2,6-dimethyl-1,4-benzoquinone, and 1,4-naphthoquinone
Handa, M
Matsumoto, H
Yoshioka, D
Nukada, R
Mikuriya, M
Hiromitsu, I
Kasuga, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (08) : 1811 - 1816
[4] Polynuclear chain complexes of ruthenium(II, III) pivalate dimers linked by 2,5-dimethyl-N,N′-dicyanobenzoquinonediimine, 1,4-benzoquinone and 1,4-naphthoquinone
Yoshioka, D
Handa, M
Mikuriya, M
Hiromitsu, I
Kasuga, K
MATERIALS SCIENCE-POLAND, 2005, 23 (03): : 765 - 771
[5] Halogenation of N-substituted p-quinone imines and p-quinone oxime esters: IV. Chlorination and bromination of N-arylsulfonyl-2(3)-methyl(2-chloro)-1,4-benzoquinone monoimines
A. P. Avdeenko
S. A. Konovalova
Russian Journal of Organic Chemistry, 2006, 42 : 349 - 364
[6] Halogenation of N-substituted p-quinone imines and p-quinone oxime esters:: IV.: Chlorination and bromination of N-arylsulfonyl-2(3)-methyl(2-chloro)-1,4-benzoquinone monoimines
Avdeenko, AP
Konovalova, SA
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 42 (03) : 349 - 364
[7] Synthesis and dienophilic behavior of (S)-2-cyano-3-(p-tolylsulfinyl)-1,4-benzoquinone
Ruano, JLG
Alemparte, C
JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (04): : 1405 - 1408
[8] 2-SUBSTITUTED AND 2,6-DISUBSTITUTED 1,4-BENZOQUINONE 4-OXIMES (P-NITROSOPHENOLS)
NORRIS, RK
STERNHEL.S
AUSTRALIAN JOURNAL OF CHEMISTRY, 1969, 22 (05) : 935 - &
[9] Halogenation of N-substituted p-quinone monoimines and p-quinone monooxime esters: X. Halogenation of N-aroyl-2,5(2,3)-dialkyl-1,4-benzoquinone monoimines and their reduction products
Avdeenko, A. P.
Konovalova, S. A.
Ludchenko, O. N.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 45 (12) : 1799 - 1813
[10] Halogenation of N-substituted p-quinone monoimines and p-quinone monooxime esters: X. Halogenation of N-aroyl-2,5(2,3)-dialkyl-1,4-benzoquinone monoimines and their reduction products
A. P. Avdeenko
S. A. Konovalova
O. N. Ludchenko
Russian Journal of Organic Chemistry, 2009, 45 : 1799 - 1813

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