Comparative investigation of CoFe2O4/CuAl2O4/CeO2/TiO2 ceramic nanocomposites prepared through various methods as catalysts for NH3-SCR

被引:2
|
作者
Salehirad, Alireza [1 ]
Latifi, Seyed Mahdi [1 ]
Zabihi, Vahid [2 ]
机构
[1] Iranian Res Org Sci & Technol IROST, Dept Chem Technol, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem Engn, Dezful Branch, Dezful, Iran
基金
美国国家科学基金会;
关键词
Ceramic nanocomposite; Catalyst; Preparation method; NH3-SCR; Structural properties; CU/TIO2; CATALYST; REDUCTION; NOX; NH3; PERFORMANCE; SPINEL; OXIDE; MECHANISM; MN; CO;
D O I
10.1007/s41779-021-00650-w
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
For comparison purposes, CoFe2O4/CuAl2O4/CeO2/TiO2 ceramic nanocomposites fabricated by four approaches have been utilized as catalysts for selective catalytic reduction of NO by NH3 (NH3-SCR). The studies specified that the preparation method had a high impact on structural properties and thereby the catalytic performance of the samples. The physical-chemical characteristics of the catalyst nanocomposites including molar ratio of metals, phase composition, crystallite size, particle size distribution, specific surface area, average pore diameter, pore volume, and agglomeration degree have been distinguished. From the comparison of structural and catalytic properties of the synthesized nanocomposites, it was identified that the sample prepared by mixing CoFe2O4 precursor with other components had the best physicochemical properties and thereby the highest NH3-SCR performance.
引用
收藏
页码:1453 / 1461
页数:9
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