Synthesis and reactivity of ferrocenecarboxylate Ruthenium(II) complexes. Catalytic synthesis of a ferrocenecarboxylic enol ester

被引:23
|
作者
Matas, L
Moldes, IA
Soler, J
Ros, J [1 ]
Alvarez-Larena, A
Piniella, JF
机构
[1] Univ Autonoma Barcelona, Dept Quim, Bellaterra 08193, Spain
[2] Univ Autonoma Barcelona, Unit Cristallog, Bellaterra 08193, Spain
关键词
D O I
10.1021/om9804069
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New ferrocenecarboxylate ruthenium(II) complexes were obtained from the reaction of[RuClH(CO)(PPh3)(3)] with ferrocenecarboxylic acid or its sodium salt. The reaction of alkenyl complexes [Ru(O2C(C5H4)Fe(C5H5))(CR'=CRH)(CO)(PPh3)(2)] with CO and catalytic synthesis of the phenylethyleneferrocenecarboxylic ester have been studied.
引用
收藏
页码:4551 / 4555
页数:5
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