The crystal structure of trans-[{Rh(μ-Cl)(CO)(coe)}2] (coe = cis-cyclooctene)

被引：0
|
作者：
Boettcher, Hans-Christian [1 ]
Mayer, Peter [1 ]
机构：
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2008年 / 63卷 / 03期
关键词：
rhodium; carbonyl; olefin complex; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of trans-[{Rh(mu-Cl)(CO)(coe)}(2)] (1) obtained from the reaction of [{Rh(mu-Cl)(coe)(2)}(2)] (coe = cis-cyclooctene) with carbon monoxide have been analyzed by X-ray crystallography (monoclinic, C2/c, Z = 4, a = 15.6271(4), b = 13.6943(4), c = 10.4169(2) angstrom; beta = 115.3549(17)degrees; V 2014.50(9) angstrom(3); T=200(2)K).
引用
收藏
页码：342 / 344
页数：3
相关论文
共 50 条
  • [1] Coordination behavior of tBu2 PH towards [{Rh(μ-Cl)(coe)2}2] (coe = cis-cyclooctene):: Crystal and molecular structure of [{Rh(μ-Cl)(tBu2PH)2}2]
    Boettcher, Hans-Christian
    Mayer, Peter
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2008, 63 (09): : 1035 - 1039
  • [2] Novel reactivity of unconjugated diimines with [PtCl2(coe)]2 (coe=cis-cyclooctene)
    Derrah, EJ
    Zhang, HW
    Nikolcheva, LG
    Vogels, CM
    Decken, A
    Westcott, SA
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (08) : 1086 - 1090
  • [3] Synthesis and molecular structure of [Rh(η5-C5H5)(coe)(PtBu2H)] (coe = cis-cyclooctene)
    Boettcher, Hans-Christian
    Mayer, Peter
    Beck, Daniel
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2019, 74 (05): : 455 - 457
  • [4] Synthesis and Molecular Structures of [Rh(η5-C5H5)(coe)2] (coe = cis-cyclooctene) and [Rh(η5-C5H5)(cod)] (cod = cis,cis-η4-1,5-cyclooctadiene)
    Graf, Marion
    Boettcher, Hans-Christian
    Mayer, Peter
    Scheer, Manfred
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2017, 643 (21): : 1323 - 1325
  • [5] Synthesis and molecular structure of trans-IrCl(coe)(tBu2PH)2] (coe = cis-cyclooetene)
    Boettcher, Hans-Christian
    Graf, Marion
    Karaghiosoff, Konstantin
    Mayer, Peter
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (5-6): : 913 - 916
  • [6] Synthesis, characterisation and molecular structure of [Rh(COE)2(acac)] (COE = cyclooctene, η2-C8H14), an important starting material for the preparation of rhodium catalyst precursors
    Burke, JM
    Coapes, RB
    Goeta, AE
    Howard, JAK
    Marder, TB
    Robins, EG
    Westcott, SA
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 649 (02) : 199 - 203
  • [7] PREPARATIONS, PROPERTIES, AND CRYSTAL-STRUCTURES OF TRANS-[RH(CN)2(NH3)4]CL-H2O AND TRANS-[RH(CN)2(EN)2]CL
    YOSHIDA, K
    KITADA, T
    ODANO, N
    KASHIWAGI, M
    HARADA, K
    URUSHIYAMA, A
    NAKAHARA, M
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (03) : 895 - 900
  • [8] Equilibrium, solid state behavior and reactions of four and five co-ordinate carbonyl stibine complexes of rhodium.: Crystal Structures of trans-[Rh(Cl)(CO)(SbPh3)2], trans-[Rh(Cl)(CO)(SbPh3)3] and trans-[Rh(I)2(CH3)(CO)(SbPh3)2]
    Otto, S
    Roodt, A
    [J]. INORGANICA CHIMICA ACTA, 2002, 331 (01) : 199 - 207
  • [9] CRYSTAL STRUCTURE OF TRANS-DICYANOBIS(ETHYLENEDIAMINE)-COBALT(III) CHLORIDE, TRANS-[CO(CN)2 EN2]CL
    OKAMOTO, T
    MATSUMOT.K
    KUROYA, H
    [J]. NIPPON KAGAKU ZASSHI, 1970, 91 (07): : 650 - +
  • [10] A crystallographic and DFT study on Vaska-type trans-[Rh(CO)Cl(PR3)2] complexes containing flexible ligands:: The molecular structure of trans-[Rh(CO)Cl{P(OC6H5)3}2]
    Muller, Alfred
    Meijboom, Reinout
    Roodt, Andreas
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (26) : 5782 - 5789
12345