Synthesis and characterization of octakis-(9-anthracenylmethylthio) substituted novel porphyrazines

被引：17

作者：

Gonca, Erguen ^{[1
]}

机构：

[1] Fatih Univ, Dept Chem, TR-34500 Istanbul, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2008年 / 33卷 / 05期

关键词：

D O I：

10.1007/s11243-008-9078-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A magnesium porphyrazinate carrying eight (9-anthracenyl) units on the periphery through flexible methylthio-bridges has been synthesized by cyclotetramerization of 3,4-(9-anthracenylmethylthio) pyrroline-2,5-diimine in the presence of magnesium butanolate. The metal-free derivative was obtained by treatment with trifluoroacetic acid and further reaction of this product with copper(II) acetate, zinc(II) acetate, and cobalt(II) acetate led to the metal porphyrazinates (M = Cu, Zn, Co). These novel compounds were characterized by elemental analysis, together with FT-IR, H-1-NMR, UV-Vis, and mass spectral data.

引用

页码：547 / 551

页数：5

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